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The spray development, combustion and emissions in a 1.9L optical, four-cylinder, direct-injection diesel engine were investigated by means of pressure analysis, high-speed cinematography, the two-colour method and exhaust gas analysis for various levels of exhaust gas recirculation (EGR), three EGR temperatures (uncontrolled, hot and cold) and three fuels (diesel, n-heptane and a two-component fuel 7D3N). Engine operating conditions included 1000 rpm/idle and 2000 rpm/2bar with EGR-rates ranging from 0 to 70%. Independent of rate, EGR was found to have a very small effect on spray angle and spray tip penetration but the auto-ignition sites seemed to increase in size and number at higher EGR-rates with associated reduction in the flame luminosity and flame temperature, by, say, 100K at 50% EGR.

The formation of soot during the first phase and the oxidation of soot during the later phase of the combustion in a direct-injection diesel engine have been investigated in detail by an extinction method. The experiments were performed in a 1.9 l near-production high-speed four-cylinder in-line direct-injection diesel engine for passenger cars for different rates of exhaust gas recirculation (EGR) and for different fuels. The measurements result in crank angle resolved and cycle-averaged soot mass concentrations in the piston bowl and the combustion chamber. The results show that with increasing EGR-rates the amount of soot formed is increased only slightly but the amount of soot oxidized during combustion decreases significantly. This is assumed to be the main reason for the increase of soot in the exhaust gas with increasing EGR-rates.

A recently developed Laser Raman Scattering system was applied to measure the in-cylinder air-fuel ratio and the residual gas content (via the water content) of the charge simultaneously in a firing spark-ignition engine during cold start and warm-up. It is the main objective of this work to elucidate the origin of misfires and the necessity to over-fuel at cool ambient temperatures. It turns out that the overall air-fuel ratio and residual gas content (in particular the residual water content) of the charge appear to be the most important parameters for the occurrence of misfires (without appropriate fuel enrichment), i.e., the engine behaviour from cycle to cycle becomes rather predictable on the basis of these data. An alternative explanation for the necessity to over-fuel is given.

The NO formation is essentially determined by the flame temperature. In an engine the latter depends on the composition of the fuel and the intake gas. In this study the efficiency of various NO reducing measures is analysed by means of a comparison of measurements and computations for the Most frequent operation point of a 1.9 1 DI Diesel engine. The O2 concentration, which is shown to be the dominant source of influence on the flame temperature and NO formation, is varied using synthetic gas mixtures or by EGR. The molar heat capacity of CO2 and H2O in the recirculated exhaust gas, the intake temperature and the H/C ratio in the fuel are less important for the formation of NO. Measures which reduce the NO formation increase the ignition delay and thereby the fraction of the premixed combustion. The impact of EGR on the combustion process is illustrated by high speed filming.

Within the European research programme IDEA (Integrated Diesel European Action), detailed experimental and theoretical studies of the fundamental phenomena of the Diesel engine like flow, injection, mixture formation, auto-ignition, combustion and pollutant formation were carried out to improve knowledge and to set up models for a simulation code. Because this basic research of the Diesel combustion process is very complex and cost intensive, it was carried out jointly by the JRC (Joint Research Committee), an association of European car manufacturers (Fiat, Peugeot SA, Renault, Volvo and Volkswagen). The activities were also subsidized by the Commission of the European Communities and the Swedish National Board of Technical Development. The results of the research work will support the design of even more efficient engines and the further reduction of soot and NOx emissions and will also enable the companies to reduce time and cost in developing new engines.

VOLKSWAGEN has conducted a number of investigations on a Multi Fuel Vehicle (MFV), designed for variable fuel operation, to determine the influence of fuel composition and clean fuels on exhaust emissions, mainly on ozone forming potential. Results of the tests indicate a small advantage of Phase II Reformulated Gasoline and a greater one for for methanol fuel M85, compared to today's gasoline. For M85 there is an about 25 % lower ozone forming potential. The most critical components in the exhaust of methanol fueled vehicles (M85) are unburned methanol and formaldehyde, forming more than 60 % of the total ozone forming potential. Therefore improvement of cold start and warmup driving during the first two to three minutes is of great importance, because in this time about 90 % of the mentioned components are formed.

A new method has been designed to examine car seats by technical means only, whether they fit summer conditions or not. Test procedures start with the application of a carefully wetted cloth onto the seat to be examined. The test area is then covered by a temperature controlled, electrically heated solid body bloc. This simulates the body temperature and the seat pressure of a real seat user. During test periods of standard three hours, temperature and humidity is measured beneath the test device and in the surrounding air. As an effect of the water impulse the humidity increases under the body bloc. It has been proved that good summer suitability of a car seat is characterised by moderate amount and moderate duration of increased humidity readings. Poor suitability results in higher amount and longer duration of raised humidity. The method is shown to be useful to examine full scale car seats, child safety seats and single design characteristics of car seats as well.

An overview is given on the state of the art of a new catalytic exhaust gas aftertreatment device for diesel engines. The function of a precious metal based, flow-through type diesel oxidation catalyst is explained. Much attention is paid to the durability of the diesel oxidation catalyst and especially to the influence of poisoning elements on the catalytic activity. Detailed data on the interaction of poisoning elements such as sulfur, zinc and phosphorus with the catalytic active sites are given. Finally it is demonstrated that it is possible to meet the stringent emission standards for diesel passenger cars in Europe with a new catalyst generation over 80.000 km AMA aging.

Several different possibilities will be described and discussed on the processes of reducing NOx in lean-burn gasoline and diesel engines. In-company studies were conducted on zeolitic catalysts. With lean-burn spark-ignition engines, hydrocarbons in the exhaust gas act as a reducing agent. In stationary conditions at λ = 1.2, NOx conversion rates of approx. 45 % were achieved. With diesel engines, the only promising variant is SCR technology using urea as a reducing agent. The remaining problems are still the low space velocity and the narrow temperature window of the catalyst. The production of reaction products and secondary reactions of urea with other components in the diesel exhaust gas are still unclarified.